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Show moreThe Ag/AgCl reference electrode is commonly used in choline chloride based deep eutectic solvents. However, we found it undergoes significant potential shifts in electrochemical tests which previous reports largely ignored. In this work, we studied the degradation mechanism leading to its instability. Results show that due to the high Cl− concentration in ethaline, the AgCl film easily dissolves and forms AgCl2 − species causing a potential shift. Therefore, we suggest a [Fe(CN)6]3−/[Fe(CN)6]4− reference electrode based on the reversibility and low diffusivity of [Fe(CN)6]3−/[Fe(CN)6]4− redox couple in ethaline, which was demonstrated to be reliable and stable over weeks of operation.
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Show moreThe discovery of electrolytes that have low vapor pressures and high solubility towards redox active species with an ability to undergo multiple electron transfer reactions is a challenge to realize in large-scale energy storage. Herein, we investigate the feasibility of (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) derived halide salts as redox active species in ethaline (1 : 2 ethylene glycol : choline chloride), a deep eutectic solvent (DES). Hydrogen bonding and electrostatic interactions achieved by the functionalization of TEMPO are shown to improve solubility in ethaline. This is the first study evaluating the physical properties and electrochemical behavior of the newly synthesized TEMPO-salts in ethaline providing insight into the impact of chemical functionality on the utility of these redox active species in DESs.
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